Diffusion with simultaneous immobilization in polymer–dye systems. I. Diffusion of the cationic dye anilana red BL in the anionically modified polyester fiber dilana

The diffusion coefficient of the cationic dye Anilana Red BL in the anionically modified polyester fiber Dilana has been calculated regarding a general diffusion-immobilization model. In the model the mobile species are distinguished from the immobilized ones. In computations of Sand's equation and experimentally determined sorption isotherm of the dye in the fiber, the rate-of-dyeing curve and the concentration profiles of the dye in the same fiber were employed. The diffusion coefficient of the mobile species of Anilana Red BL in the fiber is two orders of magnitude higher than the average diffusion coefficient obtained from Hill's equation and the apparent diffusion coefficient calculated by the Boltzmann–Matano method.     

Water quality assessment of a recently refilled reservoir: The case of Bütgenbach Reservoir, Belgium

Bütgenbach Reservoir is situated in the High Ardennes plateau in eastern Belgium (50°25′N; 6°13′E). It is used principally for flood control and for production of hydroelectric energy. It has been subjected to a previous series of studies because of its eutrophication problems and their impacts on the local economy. Bütgenbach Reservoir was emptied during spring 2004 for dam restoration, being refilled in mid‐September of the same year. Selected physicochemical and biological parameters (temperature, dissolved oxygen, pH, inorganic and organic nutrients, chlorophyll‐a) were measured fortnightly during the lake's productive season (mid‐April to mid‐October 2005) at three sampling sites throughout the water column. The water quality conditions after refilling of the lake were compared to previous studies accomplished at the same sampling sites (prior to emptying the lake). The actual trophic status was mesotrophic to eutrophic, based on the combination of total phosphorous and chlorophyll‐a concentrations, as well as water transparency. Bütgenbach Reservoir generally exhibits good water quality, based on the French water quality system SEQ‐eau. A longitudinal decrease in water quality was observed from upstream to downstream, because mainly of the differences in lake bottom morphology and water residence time, and their impacts on nutrient distribution in the lake.     

Direct Methods Optimised for Solving Crystal Structure by Powder Diffraction Data: Limits,Strategies, and Prospects

The ab-initio crystal structure solution by powder diffraction data requires great efforts because of the collapse of the experimental information onto the one dimensional 2θ axis of the pattern. Different strategies will be described aiming at improving the process of extraction of the integrated intensities from the experimental pattern in order to make more straightforward the structure solution process by direct methods. Particular attention will be devoted to the EXPO program. Some of its performance will be analysed and results will be shown.     

Collaborating freight forwarding enterprises

The paper presents a model for the collaboration among independent freight forwarding entities. In the modern highly competitive transportation branch freight forwarders reduce their fulfillment costs by exploiting different execution modes (self-fulfillment and subcontraction). For self-fulfillment they use their own vehicles to execute the requests and for subcontracting they forward the orders to external freight carriers. Further enhancement of competitiveness can be achieved if the freight forwarders cooperate in coalitions in order to balance their request portfolios. Participation in such a coalition gains additional profit for the entire coalition and for each participant, therefore reinforcing the market position of the partners. The integrated operational transport problem as well as existing collaboration approaches are introduced. The presented model for collaboration is based on theoretical foundations in the field of combinatorial auctions and operational research game theory. It is applicable for coalitions of freight forwarders, especially for the collaboration of Profit Centres within large freight forwarding companies. The proposed theoretical approach and the presented collaboration model are suitable for a coalition of freight forwarding companies with nearly similar potential on the market.     

Spectral nephelometry for making extravirgin olive oil fingerprints

In spectral nephelometry, absorption spectroscopy and nephelometry are innovatively combined to provide simultaneous online monitoring of color and turbidity of edible oils. Spectral nephelometry instrumentation consists of an optoelectronic device that measures the absorption spectrum of the oil sample at different angles. Data processing, carried out by principal component analysis (PCA), allows identification of the oil sample and creates a two-dimensional map as a fingerprint of oil types.     

Laser irradiation of oligosiloxane copolymer thin films functionalized with side chain bulky carbosilane moieties

Linear oligosiloxanes functionalized with bulky side chain tris(trimethylsilyl)hexyl (TTSH) substituents were transformed into cross-linked materials by UV 193 nm excimer pulsed laser ablation. The process occurred without any catalyst, by reactions of radicals formed in UV laser induced photolysis of side tris(trimethylsilyl)hexyl groups. Chemical changes were monitored by FTIR, LC/UV, GC/MS and solubility tests.